Paola Ceroni

620.1/92

23

Hardcover

0470433558

9780470433553

Yes

Scholarly & Professional

1.3 in

9.6 in

33.8 Oz

6.3 in

TP1180.D45

2011-021419

English

616 Pages

Designing Dendrimers

2011

Wiley & Sons, Incorporated, John

Nanoscience, Biotechnology, Chemistry / General

Science, Medical

"Congratulations to the editors (and the prominent authors) on this new volume addressing dendrimers. It contains valuable summaries on state-of-the-art design, synthesis, analysis, and applications of this structural type that occurs within small, medium nano-sized, and large, multi-branched, functional molecules. It also demonstrates that there are numerous experimental options and much work left to be done in the future." Dr. Fritz VÖgtle, University of Bonn, Germany A unifying and comprehensive look at the study and application of dendrimers today, in the past, and in the future Research on dendrimers has exploded in recent years, moving first from the establishment of synthetic methodologies, then towards the sophisticated and wide-ranging applications of these remarkable molecules. Dendrimers play an important role in many different fields: from basic synthetic approaches to artificial photosynthesis, to medicine, and far beyond. The great potential of dendrimers is well recognized, but until now there has not been one definitive volume that covers the vast amount of information and research that has been found in thousands of papers and patents. Designing Dendrimers fills this void, covering both the fundamental and applicative aspects of dendrimer research, with chapters devoted to basic principles, synthetic methods and strategies, and advanced characterization techniques. It also addresses the full potential of dendrimers in various fields, like multi-redox pool systems, diagnostics, biomedical and sensing functions, and the design of functional nanostructures, with a particular emphasis on possible future developments., Research on dendrimers has exploded in the last 15 years, moving from the establishment of synthetic methodologies, particularly in the early years up to the end of nineties, towards sophisticated and wide-ranging applications. Dendrimers play an important role in many different areas, spanning from basic synthetic approaches to artificial photosynthesis, to medicine, to catalysis. The great potential of dendrimers is well-recognized by the hundreds of papers in the field and the increasing number of patents, and stimulated developments in other areas of knowledge, including new characterization techniques. However, some basic principles and methods still continue to give a unity to the field. Although several books on dendrimers have been published during these 15 years, the very recent progresses in new areas now requires a new point of view, trying to give a unifying and comprehensive outlook of the field. Since the first dendrimer was synthesized by Vögtle in 1978, dendrimers have experienced an explosion of scientific interest because of their unique molecular architecture. This resulted in over 5,000 scientific papers and patents published by the end of 2005. The proposed book will cover both fundamental and applicative aspects of dendrimer research. Chapters devoted to basic principles, synthetic methods and strategies, and advanced characterization techniques will be integrated by chapters illustrating the full potential of dendrimers in various fields, like artificial photosynthesis, multi-redox pool systems, diagnostics, biomedical and sensing purposes, design of functional nanostructures. Particular emphasis will be devoted to possible future developments., Research on dendrimers has exploded in the last 15 years, moving from the establishment of synthetic methodologies, particularly in the early years up to the end of nineties, towards sophisticated and wide-ranging applications. Dendrimers play an important role in many different areas, spanning from basic synthetic approaches to artificial photosynthesis, to medicine, to catalysis. The great potential of dendrimers is well-recognized by the hundreds of papers in the field and the increasing number of patents, and stimulated developments in other areas of knowledge, including new characterization techniques. However, some basic principles and methods still continue to give a unity to the field. Although several books on dendrimers have been published during these 15 years, the very recent progresses in new areas now requires a new point of view, trying to give a unifying and comprehensive outlook of the field. Since the first dendrimer was synthesized by V gtle in 1978, dendrimers have experienced an explosion of scientific interest because of their unique molecular architecture. This resulted in over 5,000 scientific papers and patents published by the end of 2005. The proposed book will cover both fundamental and applicative aspects of dendrimer research. Chapters devoted to basic principles, synthetic methods and strategies, and advanced characterization techniques will be integrated by chapters illustrating the full potential of dendrimers in various fields, like artificial photosynthesis, multi-redox pool systems, diagnostics, biomedical and sensing purposes, design of functional nanostructures. Particular emphasis will be devoted to possible future developments., Research on dendrimers has exploded in the last fifteen years, moving from the establishment of synthetic methodologies towards sophisticated applications. Designing Dendrimers covers both fundamental and applicative aspects of dendrimer research.

Preface vii List of Contributors xi 1 Dendrimers as quantized nano-modules in the nanotechnology field 1 Jørn B. Christensen and Donald A. Tomalia 2 Novel methods for dendrimer synthesis 35 Isao Washio and Mitsuru Ueda 3 Designer monomers to tailored dendrimers 57 George R. Newkome and Carol Shreiner 4 Dendronized polymers: state of the art in Zurich 95 Afang Zhang and A. Dieter Schleuter 5 Shape persistent polyphenylene-based dendrimers 121 Martin Baumgarten, Tianshi Qin, and Klaus Meullen 6 Dendrimer chemistry with fullerenes 161 Jean-Franc¸ois Nierengarten 7 Redox and fluorescent open core dendrimers 195 Angel E. Kaifer 8 Redox-active organometallic dendrimers as electrochemical sensors 219 Carmen M. Casado, Beatriz Alonso, Jose Losada, and Mari´a Pilar Garci´a-Armada 9 Shape-persistent conjugated dendrimers for organic electronics 263 Jing Yan, Fan Gao, Jian Pei, and Yuguo Ma 10 Fine-controlled metal assembly in dendrimers 303 Takane Imaoka and Kimihisa Yamamoto 11 Enlightening structure and properties of dendrimers by fluorescence depolarization 341 Giacomo Bergamini, Enrico Marchi, Paola Ceroni, and Vincenzo Balzani 12 Single-molecule spectroscopy of dendrimer systems 367 Tom Vosch 13 Degradable dendrimers 403 Marc Gingras 14 Porphyrin dendrimers as biological oxygen sensors 463 Sergei A. Vinogradov and David F. Wilson 15 Peptide dendrimers as artificial proteins 505 Tamis Darbre and Jean-Louis Reymond 16 Phosphorus-containing dendritic architectures: synthesis and applications 529 Anne-Marie Caminade and Jean-Pierre Majoral Index 563

Textbook

Wiley & Sons, Incorporated, John

9780470433553